Article

Pentanuclear tetra-decker luminescent lanthanide Schiff base complexes.

Department of Chemistry and Biochemistry, The University of Texas at Austin, Austin, Texas 78712-0165, USA.
Dalton Transactions (impact factor: 3.84). 05/2008; DOI:10.1039/b801513a pp.1676-8
Source: PubMed

ABSTRACT Luminescent pentanuclear tetra-decker Ln(III) complexes [Eu5L4(OH)2(NO3)4(H2O)2].NO3.3H2O , [Nd5L4(OH)2(NO3)5MeOH].3MeOH.2H2O and [Eu5L4(CF3SO3)4(MeO)2(H2O)4].CF3SO3.H2O are formed from Ln(NO3)3.6H2O (Ln = Eu (1), Nd (2)) and Eu(CF3SO3)3, respectively (H2L = N,N'-bis(5-bromo-3-methoxysalicylidene)phenylene-1,2-diamine).

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Keywords

Luminescent pentanuclear tetra-decker Ln(III)