Article

Efficient catalytic decomposition of CO2 to CO and O-2 over Pd/mixed-conducting oxide catalyst in an oxygen-permeable membrane reactor

State Key Laboratory of Materials-Oriented Chemical Engineering, Membrane Science and Technology Research Center, Nanjing University of Technology, 5 Xinmofan Road, Nanjing 210009, PR China.
Environmental Science and Technology (Impact Factor: 5.48). 05/2008; 42(8):3064-8. DOI: 10.1021/es702913f
Source: PubMed

ABSTRACT The thermal decomposition of CO2 to CO and O2 is a potential route for the consumption and utilization of CO2. However, this reaction is limited by both the thermodynamic equilibrium and the kinetic barrier. In this study, we reported an innovative catalytic process to decompose CO2 in an oxygen-permeation membrane reactor packed with a mixed-conducting oxide supported noble metal catalyst, or Pd/SrCo0.4Fe0.5Zr0.1O3-delta (Pd/ SCFZ), which is of high activity in the decomposition of CO2 into CO and O2. Pd/SCFZ catalyst was prepared by incipient wetness impregnation of the SCFZ powders with an aqueous solution of PdCl2, and the CO2 sorption/desorption property was examined by in situ Fourier transform infrared spectroscopy and temperature-programmed desorption-mass spectrometry technologies. It was shown that there appeared a typical of bridged carbonyls (Pd-CO) on the surface of the Pd/SCFZ catalyst formed after CO2 decomposition. Both CO2 and CO could be detected in the species desorbed from Pd/SCFZ catalyst, which implied that the Pd/SCFZ catalyst could effectively activate the CO2 molecule. During the catalytic process, furthermore, the activity of the Pd/SCFZ catalyst can self-regenerate by removing the produced lattice oxygen through the dense oxygen-permeable ceramic membrane. At 900 degrees C, this catalytic process attains 100% of CO formation selectivity at 15.8% of CO2 conversions.

3 Followers
 · 
164 Views
  • Source
    Membrane Reactors for Energy Applications and Basic Chemical Production, Edited by Basi l e & Di Paol a & Hai & Pi emonte, 01/2015: chapter Membrane reactors for the decomposition of water, nitrogen oxides, and carbon dioxide, Chapter 7; Elsevier.
  • Source
    [Show abstract] [Hide abstract]
    ABSTRACT: Electrochemical cells and systems play a key role in a wide range of industry sectors. These devices are critical enabling technologies for renewable energy; energy management, conservation, and storage; pollution control/monitoring; and greenhouse gas reduction. A large number of electrochemical energy technologies have been developed in the past. These systems continue to be optimized in terms of cost, life time, and performance, leading to their continued expansion into existing and emerging market sectors. The more established technologies such as deep-cycle batteries and sensors are being joined by emerging technologies such as fuel cells, large format lithium-ion batteries, electrochemical reactors; ion transport membranes and supercapacitors. This growing demand (multi billion dollars) for electrochemical energy systems along with the increasing maturity of a number of technologies is having a significant effect on the global research and development effort which is increasing in both in size and depth. A number of new technologies, which will have substantial impact on the environment and the way we produce and utilize energy, are under development. This paper presents an overview of several emerging electrochemical energy technologies along with a discussion some of the key technical challenges.
    Frontiers in Chemistry 09/2014; 2:79. DOI:10.3389/fchem.2014.00079
  • Source
    [Show abstract] [Hide abstract]
    ABSTRACT: To accelerate the commercial application of mixed-conducting membrane reactor for catalytic reaction processes, a robust mixed-conducting multichannel hollow fiber (MCMHF) membrane reactor was constructed and characterized in this work. The MCMHF membrane based on reduction-tolerant and CO2-stable SrFe0.8Nb0.2O3-δ (SFN) oxide not only possesses a good mechanical strength, but also has a high oxygen permeation flux under air/He gradient, which is about four times that of SFN disk membrane. When partial oxidation of methane (POM) was performed in the MCMHF membrane reactor, excellent reaction performance (oxygen flux of 19.2 ml·min−1·cm−2, hydrogen production rate of 54.7 ml·min−1·cm−2, methane conversion of 94.6% and the CO selectivity of 99%) was achieved at 1173 K. And also, the MCMHF membrane reactor for POM reaction was operated stably for 120 h without obvious degradation of reaction performance. This article is protected by copyright. All rights reserved.
    AIChE Journal 04/2015; DOI:10.1002/aic.14835 · 2.58 Impact Factor