Article

Transforming terpene-derived aldehydes into 1,2-epoxides via asymmetric α-chlorination: subsequent epoxide opening with carbon nucleophiles.

TU Dortmund University, Otto-Hahn-Straße 6, D-44227 Dortmund, Germany.
Chemical Communications (impact factor: 6.17). 11/2011; 47(44):12200-2. DOI:10.1039/c1cc15173h pp.12200-2
Source: PubMed

ABSTRACT Merging Jørgensen's and MacMillan's organocatalytic aldehyde chlorinations enables the synthesis of chiral vinylcyclopropanes and (-)-cis-aerangis lactone via terpene-derived 1,2-epoxides.

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Keywords

-)-cis-aerangis lactone
 
MacMillan's organocatalytic aldehyde chlorinations enables