Enzyme-like control of carbocation deprotonation regioselectivity in supramolecular catalysis of the Nazarov cyclization.
Department of Chemistry, University of California, Berkeley, Berkeley, CA 94720-1416, USA.Angewandte Chemie International Edition (Impact Factor: 13.73). 09/2011; 50(45):10570-3. DOI:10.1002/anie.201105325
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ABSTRACT: Twist of fate: Expanding the scope of cavity-containing compounds is essential for developing more efficient sensors and catalysts. This report describes an efficient cyclialkylation reaction that provides rapid access to a novel C(3) symmetric and chiral cavitand. The host can be prepared in larger quantities through two synthetic steps and from simple starting materials.Chemistry 06/2012; 18(27):8301-5. · 5.93 Impact Factor
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