Article

(2-Chloro-4-nitrobenzoato)(methanol)triphenyltin(IV)

Acta Crystallographica Section E Structure Reports Online (Impact Factor: 0.35). 05/2011; 67(Pt 5):m535. DOI: 10.1107/S1600536811011962
Source: PubMed

ABSTRACT In the title complex, [Sn(C(6)H(5))(3)(C(7)H(3)ClNO(4))(CH(4)O)], the five-coordinate Sn(IV) atom exists in a trigonal-bipyramidal environment, formed by a monodentate carboxyl-ate group, three phenyl rings and a methanol mol-ecule. The axial sites are occupied by the O atoms of the methanol mol-ecule and the carboxyl-ate group, while the equatorial plane is formed by the C atoms of three phenyl rings. The benzene ring of the 2-chloro-4-nitro-benzoate ligand makes dihedral angles of 66.18 (7), 74.71 (7) and 77.39 (7)° with respect to the three phenyl rings. In the crystal, the mol-ecules are linked via inter-molecular O-H⋯O and C-H⋯O hydrogen bonds into a column along the b axis.

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