Article

Synthesis of block copolymers with a pentasilane core.

Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan. .
Macromolecular Rapid Communications (Impact Factor: 4.93). 06/2009; 30(11):948-53. DOI: 10.1002/marc.200800788
Source: PubMed

ABSTRACT We report a new method for the synthesis of block copolymers with a pentasilane core by the polymerization of alkyl methacrylate monomers using the pentasilyl dianion as an initiator. The polymerization proceeded with living features and yielded the corresponding block copolymers with controlled molecular weights. The amphiphilic block copolymer was obtained by the polymer reaction, and it formed sphere-like aggregates in MeOH/H(2) O solution.

0 Bookmarks
 · 
76 Views
  • Source
    [Show abstract] [Hide abstract]
    ABSTRACT: This textbook is intended to give an understanding of the basic principles that constitute the field of non-conventional polymers containing inorganic and organometalic units as the repeating units. Each chapter will be self-explanatory with a good background so that it can be easily understood at the senior undergraduate level. The principles involved in the preparation of these polymers, their characterisation and their applications will be discussed. Basic inorganic chemistry required for the understanding of each topic is presented so that the content of the chapter is readily understood.
    Macromolecular Chemistry and Physics 05/2006; 207(10). · 2.39 Impact Factor