Article

Di-μ-chlorido-bis-({2-[(4-bromo-phen-yl)-imino-meth-yl]pyridine-κN,N'}-chloridomercury(II)).

Acta Crystallographica Section E Structure Reports Online (Impact Factor: 0.35). 01/2009; 65(Pt 8):m889. DOI: 10.1107/S1600536809025641
Source: PubMed

ABSTRACT The unique Hg(II) ion in the title centrosymmetric dinuclear complex, [Hg(2)Cl(4)(C(12)H(9)BrN(2))(2)], is in a distorted trigonal-bipyramidal coordination environment formed by the bis-chelating N-heterocyclic ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Hg-Cl bonds is significantly longer than the other.

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May 20, 2014