Article

1,4-Bis(methylsulfanyl)naphthalene

Acta Crystallographica Section E Structure Reports Online (Impact Factor: 0.35). 06/2009; 65(Pt 6):o1376. DOI: 10.1107/S1600536809018650
Source: PubMed

ABSTRACT The mol-ecule of the title compound, C(12)H(12)S(2), is close to planar, with the methyl C atoms deviating by 0.019 (1) and 0.221 (2) Å from the naphthalene mean plane. In the crystal structure, the shortest S⋯S contact of 3.6864 (9) Å is longer than the van der Waals contact distance.

1 Follower
 · 
106 Views
  • Source
    [Show abstract] [Hide abstract]
    ABSTRACT: In the title compound, C(13)H(12)O, the cyclo-pentene ring fused with the naphthalene group adopts an envelope conformation. The cyclo-pentene torsion angle, with the fusion bond at the centre, has a magnitude of 1.16 (16)°. In the crystal, neigh-bouring mol-ecules are connected through O-H⋯O hydrogen bonds into an R(4) (4)(8) ring motif. The crystal packing also features weak π-π stacking inter-actions [centroid-centroid distance = 3.8981 (8) Å] and C-H⋯π inter-actions.
    Acta Crystallographica Section E Structure Reports Online 03/2012; 68(Pt 3):o687. DOI:10.1107/S1600536812005181 · 0.35 Impact Factor
  • Source
    [Show abstract] [Hide abstract]
    ABSTRACT: In the title compound, C(26)H(24)O(2), the crowded naphthalene ring system is essentially planar [maximum deviation of 0.027 (2) Å for one of the C atoms of the unsubstituted ring]. In the crystal, mol-ecules are connected by O-H⋯O hydrogen bonds into chains along the a axis. Pairs of the oppositely oriented chains are further cross-linked by O-H⋯O hydrogen bonds, forming infinte bands of alternating R(4) (4)(8) dimers and R(2) (2)(14) motifs.
    Acta Crystallographica Section E Structure Reports Online 04/2011; 67(Pt 4):o931. DOI:10.1107/S160053681100986X · 0.35 Impact Factor

Full-text (2 Sources)

Download
74 Downloads
Available from
May 22, 2014