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Biosynthetic origin of 2-geranyl-1,4-naphthoquinone and its related anthraquinone in a Sesamum indicum hairy root culture. Phytochem

Department of Applied Biological Science, Faculty of Agriculture, Kagawa University, Kagawa 761-0795, Japan.
Phytochemistry (Impact Factor: 3.35). 04/2011; 72(9). DOI: 10.1016/j.phytochem.2011.03.012
Source: PubMed

ABSTRACT In order to clarify the biosynthetic origin of 2-geranyl-1,4-naphthoquinone and its biogenetically related anthraquinone, which are possible intermediates of anthrasesamones, [1-(13)C]glucose was administered to a hairy root culture of Sesamum indicum. The labeling patterns of these quinone derivatives indicated that the naphthoquinone ring and geranyl side-chain of geranylnaphthoquinone were respectively biosynthesized through the shikimate and methylerythritol phosphate pathways, and that these quinone derivatives have the same biosynthetic origin.

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