Spectral Analysis of Oxygen Radical in a Synergistic System of Pulsed Discharge Plasma/TiO2
ABSTRACT Based on the synergistic effect of pulsed discharge plasma and titanium dioxide (TiO2) photocatalysis, a coupling system of pulsed discharge plasma/TiO2 was set up in the present paper, by using the ultraviolet radiation produced during the pulsed discharge process. TiO2 film immobilized on the glass beads was used as the photocatalyst in the synergistic system. In the research, the synergistic mechanism of pulsed discharge plasma and TiO2 photocatalysis was reviewed by the spectral diagnosis of oxygen radical (* O radical) produced in different reaction systems. The obtained results showed that the characteristic emission spectrum of * O radical could be observed at 777 nm and the corresponding transitions was 3p5 P --> 3s5 S. When air was used as bubbling gas, the relative emission intensity of * O radical recorded in the synergistic system was stronger than that in the plasma alone system, and the same result was also obtained when oxygen (O2) was used as bubbling gas. This result revealed that the photocatalytic activity of the immobilized TiO2 in the synergistic system could be induced by the ultraviolet radiation formed during the pulsed discharge process. In the systems of pulsed discharge plasma alone and pulsed discharge plasma combined with TiO2 photocatalysis, the relative emission intensity of * O radical in distilled water was stronger than that in phenol solutions. The results showed that * O radical was one of responsible radicals for phenol degradation in the pulsed discharge plasma alone system as well as the synergistic system.
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ABSTRACT: This paper presents the review of the effects of operating parameters on the photocatalytic degradation of textile dyes using TiO2-based photocatalysts. It further examines various methods used in the preparations of the considered photocatalysts. The findings revealed that various parameters, such as the initial pH of the solution to be degraded, oxidizing agents, temperature at which the catalysts must be calcined, dopant(s) content and catalyst loading exert their individual influence on the photocatalytic degradation of any dye in wastewaters. It was also found out that sol-gel method is widely used in the production of TiO2-based photocatalysts because of the advantage derived from its ability to synthesize nanosized crystallized powder of the photocatalysts of high purity at relatively low temperature.Journal of hazardous materials 06/2009; 170(2-3):520-9. DOI:10.1016/j.jhazmat.2009.05.039 · 4.33 Impact Factor
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ABSTRACT: Sonochemical processes have been widely used in chemistry and chemical engineering field. Recently, these processes have found new applications in the environmental field, because of advantages in terms of operational simplicity, secondary pollutant formation and safety. Several studies have reported on sonochemical degradation of organic compounds that are toxic in nature. The objective of this review was to identify and examine some of the studies on sonochemical degradation of chlorinated organic compounds, phenolic compounds and organic dyes. This review also examines the basic theory of sonochemical reactions and the use of sonochemical reactors for environmental applications.Science of The Total Environment 03/2009; 407(8):2474-92. DOI:10.1016/j.scitotenv.2008.12.031 · 4.10 Impact Factor
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