Article

Rh(I)-catalyzed olefin hydroarylation with electron-deficient perfluoroarenes.

Department of Chemistry and Molecular Biology, North Dakota State University, Fargo, North Dakota 58102, USA.
Journal of the American Chemical Society (impact factor: 9.91). 05/2010; 132(20):6935-7. DOI:10.1021/ja102575d pp.6935-7
Source: PubMed

ABSTRACT Assisted by a partially aqueous media, a catalyst system of [Rh(cod)(OH)](2) and DPPBenzene ligand effectively promotes direct conjugate additions by perfluoroarenes. This formal C-H alkylation process represents a rare example of olefin hydroarylation with electron-deficient arenes. The catalyst system can be modified to selectively form the corresponding olefination products under anhydrous conditions.

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Keywords

aqueous media
 
corresponding olefination products
 
electron-deficient arenes
 
formal C-H alkylation process
 
olefin hydroarylation
 
perfluoroarenes
 

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