Article

Copper-catalyzed direct alkynylation of electron-deficient polyfluoroarenes with terminal alkynes using O2 as an oxidant.

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.
Journal of the American Chemical Society (Impact Factor: 10.68). 03/2010; 132(8):2522-3. DOI: 10.1021/ja910461e
Source: PubMed

ABSTRACT A copper-catalyzed direct alkynylation of electron-deficient polyfluoroarenes with a wide range of terminal alkynes is realized for the first time. The reaction proceeds under mild conditions with O(2) as an oxidant.

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