Valence bond and von Neumann entanglement entropy in Heisenberg ladders.
ABSTRACT We present a direct comparison of the recently proposed valence bond entanglement entropy and the von Neumann entanglement entropy on spin-1/2 Heisenberg systems using quantum Monte Carlo and density-matrix renormalization group simulations. For one-dimensional chains we show that the valence bond entropy can be either less or greater than the von Neumann entropy; hence, it cannot provide a bound on the latter. On ladder geometries, simulations with up to seven legs are sufficient to indicate that the von Neumann entropy in two dimensions obeys an area law, even though the valence bond entanglement entropy has a multiplicative logarithmic correction.
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ABSTRACT: We study the von Neumann block entropy in the Kondo necklace model for different anisotropies η in the XY interaction between conduction spins using the density matrix renormalization group method. It was found that the block entropy presents a maximum for each η considered, and, comparing it with the results of the quantum criticality of the model based on the behavior of the energy gap, we observe that the maximum block entropy occurs at the quantum critical point between an antiferromagnetic and a Kondo singlet state, so this measure of entanglement is useful for giving information about where a quantum phase transition occurs in this model. We observe that the block entropy also presents a maximum at the quantum critical points that are obtained when an anisotropy Δ is included in the Kondo exchange between localized and conduction spins; when Δ diminishes for a fixed value of η, the critical point increases, favoring the antiferromagnetic phase.Physical Review A 06/2010; 81(6). · 3.04 Impact Factor
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ABSTRACT: We present an exact expression for the entanglement entropy generated at a quantum point contact between noninteracting electronic leads in terms of the full counting statistics of charge fluctuations, which we illustrate with examples from both equilibrium and nonequilibrium transport. The formula is also applicable to ground-state entanglement entropy in systems described by noninteracting fermions in any dimension, which in one dimension include the critical spin-1/2 XX and Ising models where conformal field theory predictions for the entanglement entropy are reproduced from the full counting statistics. These results may play an important role in experimental measurements of entanglement entropy in mesoscopic structures and cold atoms in optical lattices.Physical review. B, Condensed matter 04/2011; 83. · 3.66 Impact Factor
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ABSTRACT: The set of valence-bond states --- states in which localized spin-1/2 particles are correlated in singlet pairs said to be connected by valence bonds --- provides a useful basis for visualizing singlet ground states of quantum spin systems. For example, the ground state of the uniform one-dimensional nearest-neighbor spin-1/2 antiferromagnetic (AFM) Heisenberg model (the prototypical spin-liquid state) can be viewed as a strongly fluctuating liquid of valence bonds with a power-law length distribution. This intuitive picture directly reflects the long-range spin correlations in this state, as well as the existence of gapless excitations created by breaking long bonds. Valence-bond states also play a key role in describing the physics of random spin-1/2 AFM Heisenberg chains. For these systems, it was shown by Fisher, using a real space renormalization group analysis, that on long-length scales the ground state is described by a single valence-bond state known as a random singlet state. This single valence-bond state should be viewed as a caricature of the true ground state, which will certainly exhibit bond fluctuations on short-length scales. In valence-bond Monte Carlo (VBMC) simulations valence-bond states are used to stochastically sample singlet ground states of quantum spin systems. One of the appealing features of VBMC is that if one imagines viewing the sampled valence-bond states over many Monte Carlo time steps the resulting ``movie" would correspond closely to the intuitive resonating valence bond picture described above. For random Heisenberg chains (and related models) VBMC should therefore provide a useful method for directly studying the phenomenon of random singlet formation on long-length scales, while at the same time capturing the short-range fluctuations which will always be present. In this dissertation I present results of VBMC studies for a class of models which include the uniform and random spin-1/2 AFM Heisenberg chains, as well as models describing chains of interacting non-Abelian quasiparticles --- exotic quasiparticles conjectured to exist in certain fractional quantum Hall states. In addition to numerically computing and analyzing the so-called valence-bond entanglement scaling in these models, I introduce a new quantity which I refer to as the valence-bond fluctuation (the central new result and the main contribution of this dissertation). It is shown that this quantity, which is easy to compute in valence-bond Monte Carlo, provides a direct signature of random singlet phase formation by essentially allowing one to directly ``see" the ``locking" of the ground state into a particular valence-bond state on long-length scales. A detailed scaling analysis of this new quantity is then used to extract the dependence of the fluctuation length scale on disorder strength. Where possible, the results are compared to previous numerical and analytic work on the relevant models.01/2010;
arXiv:0905.4286v2 [cond-mat.str-el] 9 Jul 2009
Valence Bond and von Neumann Entanglement Entropy in Heisenberg Ladders
Ann B. Kallin,1Iv´ an Gonz´ alez,2Matthew B. Hastings,3and Roger G. Melko1
1Department of Physics and Astronomy, University of Waterloo, Ontario, N2L 3G1, Canada
2Centro de Supercomputaci´ on de Galicia, Avda. de Vigo s/n, E-15705 Santiago de Compostela, Spain
3Microsoft Research, Station Q, CNSI Building, University of California, Santa Barbara, CA, 93106
(Dated: July 9, 2009)
We present a direct comparison of the recently-proposed valence bond entanglement entropy and
the von Neumann entanglement entropy on spin 1/2 Heisenberg systems using quantum Monte
Carlo and density-matrix renormalization group simulations. For one-dimensional chains we show
that the valence bond entropy can be either less or greater than the von Neumann entropy, hence
it cannot provide a bound on the latter. On ladder geometries, simulations with up to seven legs
are sufficient to indicate that the von Neumann entropy in two dimensions obeys an area law, even
though the valence bond entanglement entropy has a multiplicative logarithmic correction.
Introduction.– Entanglement has arisen as a new
paradigm for the study of correlations in condensed mat-
ter systems. Measurements of entanglement between
subregions, chiefly using entropic quantities, have an ad-
vantage over traditional two-point correlation functions
in that they encode the total amount of information
shared between the subregions without the possibility of
missing “hidden” correlations , such as may occur in
some exotic quantum groundstates. For example spin liq-
uid states, where two-point correlation functions decay
at large lengthscales, can exhibit topological order that
is quantified by a “topological entanglement entropy” .
This and other entropic measures are typically discussed
in the context of the von Neumann entanglement entropy
(SvN), which for a system partitioned into two regions A
and B, quantifies the entanglement between A and B as
A = −Tr[ρAlnρA]. (1)
Here, the reduced density matrix ρA= TrB|ψ??ψ| is ob-
tained by tracing out the degrees of freedom of B.
The properties of SvNare well-studied in quantum in-
formation theory. In interacting one-dimensional (1D)
quantum systems, exact analytical results are known
from conformal field theories (CFT); they show that,
away from special critical points, SvN
of the boundary between A and B. This so-called area
law  is also believed to hold in many groundstates
of two dimensional (2D) interacting quantum systems,
although exact results are scarce . This has conse-
quences in the rapidly-advancing field of computational
quantum many-body theory, where it is known for exam-
ple that groundstates of 1D Hamiltonians satisfying an
area law can be accurately represented by matrix prod-
uct states . Tensor-network states and MERA give
two promising new classes of numerical algorithms 
that may allow simulations of 2D quantum systems not
amenable to quantum Monte Carlo (QMC) due to the no-
torious sign problem. However, these simulation frame-
works are constructed to obey an area law; in order
to be represented faithfully by them, a given 2D quan-
tum groundstate must have entanglement properties also
scales as the size
obeying the area law .
Unfortunately, entanglement is difficult to measure in
2D, due to the fact that QMC does not have direct access
to the groundstate wavefunction |ψ? required in Eq. (1).
In response to this, several authors [7, 8] have introduced
the concept of valence bond entanglement entropy (SVB),
defined for a spin system as
= ln(2) · NA, (2)
where NA is the number of singlets (| ↑↓? − | ↓↑?)/√2
crossing the boundary between regions A and B. Unlike
SvN, SVBcan be accessed easily in the valence-bond ba-
sis projector QMC method recently proposed by Sand-
vik . As demonstrated in Refs. [7, 8], SVBhas many
properties in common with SvN, in particular the rela-
regions “un-entangled” by valence bonds. A comparison
of the scaling of SVBfor (critical) 1D spin 1/2 Heisen-
berg chains shows good agreement with analytical results
known from CFT, however in the 2D isotropic Heisenberg
model it displays a multiplicative logarithmic correction
to the area law [7, 8]. If true also for SvN, this would
have negative consequences for the simulation of the N´ eel
groundstate using tensor-network simulations.
In this paper, we compare SVBcalculated by valence-
bond QMC to SvNaccessible through density-matrix
renormalization group (DMRG) simulations of the
Heisenberg model on N-leg ladders. For N = 1, the CFT
central charge calculated by scaling SvNshows excellent
agreement to c = 1, whereas SVBconverges to c < 1.
For N > 1, SVBis systematically greater than SvN, a
trend which grows rapidly with N. An examination of
entanglement defined by bipartitioning multi-leg ladders
shows a logarithmic correction for the valence-bond en-
tanglement entropy, SVB∝ N lnN (in agreement with
Refs. [7, 8]), however for data up to N = 7, the von Neu-
mann entanglement entropy convincingly shows a scaling
of SvN∝ N, thus obeying the area law.
Model and Methods.– We consider the spin 1/2 Heisen-
berg Hamiltonian, given by H =?
sum is over nearest-neighbor lattice sites. Geometries
B, and the fact that SVB
= 0 for
?ij?Si·Sj, where the
studied are 1D chains, and multi-leg ladders with length
L and number of legs N. We employ two complemen-
tary numerical techniques, the valence-bond basis QMC
and DMRG, both of which give unbiased approximations
to the ground state of the Hamiltonian at zero temper-
is naturally accessible through the DMRG
algorithm . At each step of the algorithm, the wave-
function of the system is approximated by keeping only
the states with largest coefficients in the Schmidt de-
composition for a given bipartition into regions A and
B ≡ ∁A. To find the basis entering the Schmidt decom-
position for region A, the reduced density matrix ρA is
calculated and diagonalized, thus allowing easy calcula-
tion of Eq. (1). The truncation of the basis implies that
only a lower bound for SvN
Ais calculated, so care must be
taken to ensure that enough of the eigenvalue spectrum is
included to converge SvN
Ato sufficient accuracy; typically
the number of states required is larger than that needed
to converge the energy alone. We have kept up to 1800
states per block for the largest ladders, with truncation
errors under 10−7in all cases.
can be calculated using the valence-bond basis
QMC proposed by Sandvik . The algorithm we use is
the simple single-projector method, with lattice geome-
tries constructed to match those used by DMRG. The
ground state of the system is projected out by repeated
application of a list of nearest-neighbor bond operators,
a number of which are changed each step. The change is
accepted with a probability of 2nb/2nawhere na(nb) is
the number of off-diagonal operators in the current (last
accepted) step. Measured quantities such as energy or
are then calculated by a weighted average over all
the valence bond states obtained by this procedure.
One-dimensional chain.– We consider first the case of
Heisenberg chains (N = 1) of length L, simulating both
open (OBC) and periodic (PBC) boundary conditions.
The DMRG algorithm requires the regions A and B to
be topologically connected, so in 1D the bipartition is
defined by a site index x with sites within the interval
[1,x] ([x + 1,L]) belonging to region A (B) [thus we can
label SAby its site index, S(x)]. We stress that the QMC
and DMRG results are on the same geometry and Hamil-
tonian, and reproduce the same ground state energies;
Figure 1 (and subsequent figures) should be considered
as exact comparisons between SVBand SvN.
The 1D Heisenberg model is known to be critical and
thus can be mapped to a 2D classical Hamiltonian at
its critical point, which can be described by CFT in the
limit L → ∞. To address finite-length chains one can
use the conformal mappings x → x′= (L/π)sin(πx/L)
for PBC, and x → 2x′for OBC. Calculations within
CFT  obey SvN(x) = (c/3)ln(x′) + S1for PBC, and
SvN(x) = (c/6)ln(2x′)+ln(g)+S1/2 for OBC, where c is
the central charge of the CFT, S1is a model-dependent
constant, and g is Ludwig and Affleck’s universal bound-
ary term .
0 102030 40
L = 128
L = 100
L = 200
L = 64
Heisenberg chain with PBC and OBC. Upper panels show
the entropies as a function of the conformal distance x′=
(L/π)sin(πx/L) for 100-site chains. Lower plots show the
central charge c, obtained by fitting the numerical data to
the CFT result, for several L. For PBC, c is calculated with
the two smallest x′points removed. For OBC, the fits depend
on the number of sites included, z, which we systematically
decrease by removing x′data points from the outside ends of
the chain. c is shown for SvN(closed symbols) and SVB(open
symbols) for system sizes L = 64 (circles), L = 100 (squares),
L = 128 (diamonds), and L = 200 (triangles)
(color online) Entanglement entropies for a 1D
Figure 1 illustrates simulation results in both cases,
the left (right) panels corresponding to PBC (OBC). For
PBC both SVBand SvNappear to fit well to the CFT
result, although SvN> SVB. The regression fit for SvN
shows very good convergence with the central charge pre-
dicted by CFT, c = 1, while the fit for SVByields a lower
value of c than predicted. For OBC both SvNand SVB
split into two branches, the upper (lower) correspond-
ing to an odd (even) number of lattice sites in A. This
reflects a well-known “dimerization” effect induced by
OBC . Notice that contrary to the PBC case, now
SvN< SVB. A regression fit of the lower branch to the
form (c/6)ln(2x′) (inset) shows excellent convergence of
SvNto the central charge predicted by CFT, c = 1, once
finite-size effects and the proximity of the data to the
open boundaries are taken into account. In contrast, SVB
deviates significantly from the CFT result, giving c > 1
when all or most data is included in the fit, changing to
c < 1 as data closest to the open boundary is systemati-
cally excluded , e.g. for z = L/2, cL→∞≈ 0.85.
Multi-leg ladders.– Moving away from the 1D chain,
one can add “legs” to the lattice in a systematic way. In
this case the sum over nearest neighbors is extended to
neighbors along rungs as well as along legs. As noted
before, DMRG imposes constraints to the subregion ge-
ometry. In multi-leg ladders we choose to sweep in a 1D
path that visits first bonds sitting in rungs rather than
50 100 150 200 250
FIG. 2: (color online) Entanglement entropies for 3-leg (left)
and 4-leg (right) ladder systems with OBC and 100 sites per
leg. For odd-leg ladders, S(x) ∝ ln(x′). The left inset shows
S(x) as a function of the conformal distance, x′, on a log
scale. For even-leg ladders, S(x ? ξ) = const. The right inset
shows the site indexing used for multi-leg ladders where the
bipartition A is shaded and labeled by x = 9.
bonds sitting in legs (see Fig. 2). DMRG computational
demands increase dramatically with the number of legs,
so in this paper we restrict ourselves to ladders with OBC
up to N = 7 legs. QMC lacks this limitation and one can
go up to N = 20 with minimal CPU effort.
Figure 2 shows SvNand SVBcalculated for the 3-leg
and 4-leg ladder. As for the OBC 1D chain, SVB> SvN.
Entropy shows different behavior depending on N being
even or odd. Even-leg ladders have a spin-gap , and
thus only sites within distances from the boundary be-
tween A and B smaller than the correlation length ξ con-
tribute to the entanglement, yielding S(x ? ξ) = const.
In contrast, odd-leg ladders are gapless, and thus all sites
contribute to the entanglement, yielding S(x) ∝ ln(x′),
which follows the CFT result in analogy to the 1D case.
As can be seen, S(x) splits into branches, with a (quasi-)
periodic structure superimposed over the main depen-
dence on x, the period being N (2N) for even- (odd-) leg
ladders. This reflects the periodicity of the underlying 1D
path through which the algorithm sweeps, and the fact
that valence bonds within the same rung are energetically
favored . The doubled period for odd-leg ladders is
due to the same dimerization effect as in Ref. .
Area law in multi-leg ladders.– We can use these results
to address the question of the adherence of the 2D N´ eel
state to an area law. To do so, we define the lattice geom-
etry such that region A is rectangular, cutting a multi-leg
ladder cleanly across all legs, so that the “area” separat-
ing region A and B is equivalent to the number of legs
in the ladder N. We choose the region A to contain 2N2
sites, to have an aspect ratio of order unity. In contrast,
the entanglement entropy of a long narrow region would
be dominated by the behavior of the gapless mode for
odd-leg ladders. The 2:1 aspect ratio makes the region
SvN(L = 100)
S(x = 2N2)/N
SVB(L = 4N)
SvN(L = 4N)
SVB(L = 100)
ff−0.3 (L = 100)
FIG. 3: (color online) Entanglement entropies divided by N,
for N-leg Heisenberg (filled symbols) and free-fermion (open
diamonds) ladders, taken such that the region A includes 2N2
sites. For the Heisenberg model and large N, SVB∝ N lnN,
whereas SvN∝ N. Data for free fermions, SvN
shown for comparison. We show data for ladders with length
(sites per leg) L = 100 and L = 4N.
∝ N lnN, are
length even for all N, reducing even-odd oscillations.
Figure 3 illustrates the simulation results for N-leg lad-
ders. Plotting S(x)/N versus N on a log scale, we obtain
a multiplicative logarithmic correction to the SVBarea
law, in agreement with results from Refs. [7, 8]. How-
ever, the linear slope is not present in the plot of the SvN
data from the DMRG, which convincingly approaches a
constant for large N . Clearly, for SvNthe area law
is indeed obeyed in the N´ eel groundstate, leading one
to conclude that the multiplicative logarithmic correc-
tion occurs in SVBonly. One can compare SVBto data
obtained for free fermions, which has a well-known 
logarithmic correction to the area law for SvN(Fig. 3).
In the next section, we explain SVBin the context of the
bond length distribution in the QMC. We note also that,
contrary to the suggestion in Ref. , a gapless Goldstone
mode will not give a logarithmic divergence to SvNsince
a gapless bosonic mode in 2D obeys an area law . We
have also done a spin-wave calculation of SvNfor this sys-
tem and found an area law, albeit with S(x)/N ≈ 0.2,
slightly lower than suggested for spin 1/2 in Fig. 3.
Bond Length Distribution.– Sandvik defined the bond
length distribution P(x,y) as the probability of a bond
going from site x to site y, and found that P(x,y) ∼
|x−y|−pwith p ≈ 3 in the N´ eel state . This value of p
gives the logarithmic divergence in SVB, as can be found
by directly calculating
We can understand the value of p from a scaling ar-
gument similar to that in Ref. . Consider the num-
ber of bonds of length l exiting a region of linear size l.
For p > 4, this scales to zero and such a state should
have no long-range order. For p = 4, this number is
l-independent, corresponding to a critical state (p = 2
is the critical power in 1D, matching the observed loga-
rithmic behavior of SVB). For p < 2, the bond length
distribution is unnormalized, and all bonds are long, so
that there is no short-range order. p = 3 represents a
state with both long- and short-range order. There is
a heuristic argument that p = 3 corresponds to a state
with Goldstone modes: the correlation function of two
spins is the probability that they lie on the same loop.
This can be estimated by the Green’s function of a L´ evy
flight with power law distributed steps with power 3, re-
producing the power law decay of correlations.
Discussion.– In this paper, we have compared scal-
ing properties of the valence bond entanglement entropy
(SVB) [7, 8] to the von Neumann entanglement entropy
(SvN) in the spin 1/2 Heisenberg model on multi-leg lad-
der geometries, using QMC and DMRG simulations. In
1D, we find that SVBmimics the behavior of SvNclosely,
although it is less than SvNfor periodic chains, and
greater than SvNfor open chains. In addition, fits to
1D conformal field theory, which are excellent for SvN
calculated via DMRG, appear to deviate significantly for
SVBin the large chain-size limit, approaching c < 1 for
both boundary conditions .
The fact that SVBcan be either greater or less than
SvNcan be understood through simple examples. Let
|(ij)(kl)...? denote a state in which sites i,j are in a
singlet, sites k,l are in a singlet, and so on. Consider
an 8-site chain, with sites 1 to 4 in region A. Then,
the state |(12)(34)(56)(78)?+|(14)(32)(58)(76)? has van-
since no bonds connect A to B, but non-
≈ 0.325. On the other hand, consider
a 4-site chain, with sites 1 and 3 in region A. Then, the
state |(12)(34)? + |(14)(32)? has a maximal SVB
to 2ln(2) ≈ 1.386, while SvN
This second state has the maximum possible N´ eel order
parameter: it is the equal amplitude superposition of all
configurations of bonds connecting the two sublattices.
Thus, it is unsurprising that states with N´ eel order show
SVB> SvN, a fact which we have demonstrated numeri-
cally on multi-leg ladder systems with open boundaries.
Defining the boundary between the two entangled re-
gions as being bipartitioned by a cut across all legs on
a ladder, we have shown using DMRG that SvNobeys
the area law in the many-leg limit. Since DMRG can
also accurately measure logarithmic size-dependencies of
SvN(in 1D critical systems), this suggests that simula-
tion procedures similar to those here might enable the
measurement of area-law corrections in SvNas indica-
tors of exotic phases in other models, such as those with
a spinon Fermi surface .
The valence bond entanglement entropy harbors a mul-
tiplicative logarithmic correction for the N´ eel ground-
state, which we have shown is caused by the valence-
bond length distribution, and is not present in SvN. It
A= ln(3) ≈ 1.099 is smaller.
is clear that SVBis a reasonable measurement of entan-
glement, readily accessible to numerical simulations in
2D and higher, and capable of reproducing the area law
in some gapped groundstates [7, 8]. However, the in-
ability of SVBto provide a bound on SvN(unlike other
measures such as Renyi entropies), along with its discrep-
ancies from SvNin 1D critical systems and the 2D N´ eel
state, must be taken into account in proposals to use SVB
for future tasks such as characterizing topological phases
or studying universality at quantum phase transitions.
Acknowledgments.– The authors thank I. Affleck,
A. J. Berlinsky, N. Bonesteel, A. Del Maestro, A. Feiguin,
M. Fisher, L. Hormozi, and E. Sørensen for useful discus-
sions. This work was made possible by the computing
facilities of SHARCNET and CESGA. Support was pro-
vided by NSERC of Canada (A.B.K. and R.G.M.) and
the NSF under Grant No. NSF PHY05-51164 (I.G.).
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