Article

Platinum(II) and palladium(II) complexes of chiral P-Cl functionalized bis-phosphino ortho-carbaboranes.

Institut für Anorganische Chemie der Universität Leipzig, Johannisallee 29, D-04103 Leipzig, Germany.
Inorganic Chemistry (impact factor: 4.6). 09/2009; 48(17):8638-45. DOI:10.1021/ic9011907 pp.8638-45
Source: PubMed

ABSTRACT Platinum(II) and palladium(II) complexes of chiral P-Cl functionalized bis-phosphino ortho-carbaborane are readily obtained from reactions of chiral bidentate phosphino carbaborane ligands rac-1,2-(PRCl)(2)(C(2)B(10)H(10)) with [MCl(2)(COD)] (M = Pd, Pt; COD = 1,5-cyclooctadiene) to give cis-rac-[MCl(2){1,2-(PRCl)(2)(C(2)B(10)H(10))}] (M = Pt, Pd; R = (t)Bu, Ph, NEt(2), NPh(2)). cis-rac-[MCl(2){1,2-(P(t)BuCl)(2)(C(2)B(10)H(10))}] [M = Pt (1), Pd (6)] decompose in solution in toluene or dichloromethane at room temperature over several weeks with formation of the corresponding dinuclear platinum and palladium complex with two nido-carbaboranyl phosphine ligands, (R(P),R(P),S(P),S(P))-[{M(7,8-{P(t)BuCl}(2)C(2)B(9)H(10))(mu-Cl)}(2)] [M = Pt (2), Pd (7)], among other decomposition products.

0 0
 · 
0 Bookmarks
 · 
22 Views
Data provided are for informational purposes only. Although carefully collected, accuracy cannot be guaranteed. The impact factor represents a rough estimation of the journal's impact factor and does not reflect the actual current impact factor. Publisher conditions are provided by RoMEO. Differing provisions from the publisher's actual policy or licence agreement may be applicable.

Keywords

6)] decompose
 
chiral P-Cl functionalized bis-phosphino ortho-carbaborane
 
COD
 
corresponding dinuclear platinum
 
dichloromethane
 
nido-carbaboranyl phosphine ligands
 
Pd
 
Platinum(II)
 

Ilham Maulana