Article

Di-tert-butyl N-[2,6-bis(methoxymethoxy)phenyl]iminodiacetate

Acta Crystallographica Section E 01/2009;
Source: DOAJ

ABSTRACT The title molecule, C20H31NO8, has pseudo-C2 symmetry about the C—N bond, with the bis(tert-butoxycarbonyl)amino group twisted from the benzene ring plane by ca 60° and the bulky tert-butoxycarbonyl (Boc) groups are orientated away from the substituted aniline group. As part of an antibacterial drug discovery programme furnishing analogues of platensimycin, we unexpectedly synthesized the bis-Boc-protected aniline.

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Keywords

antibacterial drug discovery programme furnishing analogues
 
benzene ring plane
 
bis(tert-butoxycarbonyl)amino group twisted
 
bulky tert-butoxycarbonyl
 
C—N bond
 
substituted aniline group