Twilight tropospheric and stratospheric photodissociation rates derived from balloon borne radiation measurements

ATMOSPHERIC CHEMISTRY AND PHYSICS (Impact Factor: 5.3). 04/2003; 3(2). DOI: 10.5194/acpd-2-715-2002
Source: DOAJ

ABSTRACT A new ligthweight multichannel moderate bandwidth filter instrument designed to be flown on balloons, is described. The instrument measures the radiation field within the short UV (center wavelength at 312 nm) and long UV (center wavelength at 340 nm). The angular and spectral characteristics of the instrument are discussed and the calibration procedure outlined. Measurements made during a stratospheric balloon flight at twilight conditions from Gap-Tallard, France, are presented and compared with state-of-the-art radiative transfer model simulations. The model simulations and the measurements agree within ±10% (±20%) for solar zenith angles smaller than 93° (90°) for the 340 (312) nm channel. Based on the model simulations of the measured radiation, actinic flux spectra are reconstructed. These are used to calculate various photodissociation rates.

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Available from: Arve Kylling, Sep 02, 2015
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    • "From the irradiance measurements at various altitudes, the albedo of the surface below was derived. In addition, the albedo at 312 and 340 nm was deduced from measurements of the NILU-CUBE instrument (Kylling et al., 2003a) suspended below a hot air balloon . These albedo measurements are described by Webb et al. (2005). "
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    ABSTRACT: In September 2002, the first INSPECTRO campaign to study the influence of clouds on the spectral actinic flux in the lower troposphere was carried out in East Anglia, England. Measurements of the actinic flux, the irradiance and aerosol and cloud properties were made from four ground stations and by aircraft. The radiation measurements were modelled using the uvspec model and ancillary data. For cloudless conditions, the measurements of the actinic flux were reproduced by 1-D radiative transfer modelling within the measurement and model uncertainties of about ±10%. For overcast days, the ground-based and aircraft radiation measurements and the cloud microphysical property measurements are consistent within the framework of 1-D radiative transfer and within experimental uncertainties. Furthermore, the actinic flux is increased by between 60–100% above the cloud when compared to a cloudless sky, with the largest increase for the optically thickest cloud. Correspondingly, the below cloud actinic flux is decreased by about 55–65%. Just below the cloud top, the downwelling actinic flux has a maximum that is seen in both the measurements and the model results. For broken clouds the traditional cloud fraction approximation is not able to simultaneously reproduce the measured above-cloud enhancement and below-cloud reduction in the actinic flux.
    Atmospheric Chemistry and Physics 08/2005; 5(7):1975-1997. DOI:10.5194/acp-5-1975-2005 · 5.51 Impact Factor
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    • "The effects of atmospheric sphericity have been studied using multidimensional models with radiative transfer schemes for a spherical atmosphere or with a pseudospherical approximation. The performance of such schemes has been justified by many previous studies [Lary and Pyle, 1991a, 1991b; Lary et al., 1991; Perner et al., 1991; Dahlback and Stamnes, 1991; Dvortsov et al., 1992; Müller et al., 1994; Rattigan et al., 1996; Chipperfield et al., 1998; Kylling et al., 2003]. [3] Recently, the effects of atmospheric sphericity on the dynamics and chemistry of the global lower stratosphere have been studied by Lamago et al. [2003] with a coupled chemistry-climate model. "
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    ABSTRACT: 1] Atmospheric sphericity is an important factor that must be considered in order to evaluate an accurate ozone loss rate in the polar stratosphere. The built-in plane-parallel radiative transfer scheme of a nudging chemical transport model (CTM) and an atmospheric general circulation model (AGCM) with coupled chemistry is modified by a pseudospherical approximation. The plane-parallel atmosphere radiative transfer version (PPA version) is compared with the pseudospherical atmosphere radiative transfer version (SA version) for both the nudging CTM and AGCM. The nudging CTM can isolate the chemical effects for a given dynamical field, while the interaction among the chemical, radiative, and dynamical processes can be studied with the AGCM. The present analysis focuses on Antarctica during an ozone hole period. In the ozone loss period over Antarctica, ozone starts to decrease earlier and minimum value of total ozone becomes lower in the SA versions of both the nudging CTM and the AGCM than in the corresponding PPA versions. The ozone mixing ratio decreases earlier in the SA version because of an earlier increase of ClO concentration initiated by the upward actinic flux at solar zenith angles greater than 90°. Dynamics plays an important role as well as the chemical processes. During the ozone recovery period, the ozone distribution becomes almost the same in the SA and PPA versions of the nudging CTM, while in the AGCM the ozone amount in the SA version remains at lower values compared to those of the PPA version. In the AGCM, a decrease of ozone over Antarctica enhances the latitudinal gradient of temperature and thus strengthens the polar vortex in the SA version. A resultant delay of the polar vortex breakup causes the delay of the ozone recovery. For the AGCM, ensemble runs are performed. The ensemble experiment exhibits large ozone variances after the middle of December, when the ozone recovery is dynamically controlled. Most ensemble members of the AGCM show a delay of the polar vortex breakup in the SA version, while a few members show opposite results. In the latter members, the polar vortex breakup is strongly affected by the enhanced EP flux from the troposphere around 100 hPa, which causes the variances in the ozone recovery period. Most members, however, do not show large statistical variances; that justifies the conclusions from the ensemble means.
    Journal of Geophysical Research Atmospheres 01/2005; 110. DOI:10.1029/2005JD005798 · 3.44 Impact Factor
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    ABSTRACT: During the INSPECTRO campaign effective surface albedo was measured at UV and visible wavelengths from two airborne platforms, a Cessna light aircraft and a hot air balloon. On board the Cessna was a scanning spectroradiometer measuring from 300 - 500nm at 10nm intervals. The NILU cube, with 6 faces and two UV channels at 312 and 340nm, was suspended beneath the hot air balloon. Flights took place over East Anglia during September, 2002. Balloon flights were made below cloud layers, while the Cessna flew both above and below cloud. The Cessna also flew over Barton Bendish, where surface albedos have been measured for ground truthing of satellite data, and measured the effective albedo at four visible wave- lengths in the centres of the satellite bandpass functions. Results of measurements from the different platforms are compared, and model simulations used to deduce the surface albedo from the effective albedo at altitude, giving, for example, an albedo of 0.02 ± 0.01 at 340nm.
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