A significant enhancement of catalytic activities in oxidation with H2O2 over the TS-1 zeolite by adjusting the catalyst wettability

Chemical Communications (Impact Factor: 6.83). 01/2014; 50(16). DOI: 10.1039/c3cc48220k
Source: PubMed


Hydrophilic TS-1 (H-TS-1) with rich hydroxyl groups, which were confirmed by (29)Si and (1)H NMR techniques, exhibits much higher activities in the oxidation than conventional TS-1. This phenomenon is strongly related to the unique features of high enrichment of H2O2 on H-TS-1.

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