Article

C-H activation in strongly acidic media. The co-catalytic effect of the reaction medium.

Materials and Process Simulation Centre (MC-139-74), California Institute of Technology, Pasadena, CA, 91125, USA.
Chemical Communications (Impact Factor: 6.38). 06/2009; DOI: 10.1039/b821854d
Source: PubMed

ABSTRACT Quantum mechanical (QM) results are used to establish the role of sulfuric acid solvent in facilitating the reaction between Pt(II)(bpym)Cl(2) (bpym = 2,2'-bipyrimidinyl) and methane; coordination of methane to the platinum catalyst is found to be catalyzed by the acidic medium.

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May 27, 2014