Formation of Five and Six-Membered Heterocyclic Rings by Radical Cyclization
ChemInform 03/2003; 34(10). DOI: 10.1002/chin.200310248
ABSTRACT For Abstract see ChemInform Abstract in Full Text.
Article: Number 76
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ABSTRACT: Enaminones are very stable compounds and can be easily prepared, starting from cheap and easily available starting materials. Therefore they constitute also excellent starting materials in organic synthesis. The selective reduction of ortho-acylated β-enaminones under mild conditions, keeping enaminone moiety intact, is reported. The appropriated conditions for cyclization of newly obtained hydroxienamides were found. Novel 1-substituted 1,2,3,4-tetrahydroisoquinolines with potential anticonvulsic activity were synthesized.Synthetic Communications 01/2012; 43(3). DOI:10.1080/00397911.2011.589020 · 0.98 Impact Factor
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