Article

Catalytic Activity of Colored Sodium Chloride for the Dehydrochlorination of t‐Butyl Chloride

Department of Chemistry, Faculty of Science, Kobe University Nada-Ku, Kobe 657, Japan
Berichte der Bunsengesellschaft für physikalische Chemie 05/2010; 90(4):353 - 356. DOI:10.1002/bbpc.19860900408 pp.353 - 356

ABSTRACT When NaCl was colored with Na vapor, X-rays and Cl2 vapor, respectively, the surface became highly active catalytically. Almost without exception, the decrease in the enhanced activity upon heating occurs in the range of the annihilation temperature of the color centers. This result indicates that both F- and V-centers in NaCl may contribute to the reaction as active sites.

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Keywords

active catalytically
 
active sites
 
Cl2 vapor
 
color centers
 
decrease
 
enhanced activity
 
Na vapor