A kinetic model for ideal plug-flow reactors
Environmental Engineering Division, Department of Civil Engineering, Istanbul Technical University, 80626 Ayazaga, Istanbul, Turkey Water Research
(Impact Factor: 5.53).
05/1989; 23(5):647-654. DOI: 10.1016/0043-1354(89)90031-6
Simultaneous differential equations of plug-flow reactors resulting from mass balances on substrate and biomass around an infinitesimal volume element are solved analytically taking the longitudinal biomass gradient into account under steady-state conditions. A relationship between substrate and biomass concentrations and an analytical solution for substrate and/or biomass concentration as a function of hydraulic residence time are developed. Design examples are given and these have shown that results of analytical solution are in good agreement with those of differential equations obtained by the finite difference method. Results of this work may help engineers to acquire a new understanding about the plug-flow reactors.
Available from: murdoch.edu.au
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ABSTRACT: Nitrogen removal from wastewater is important for the revention of significant health and environmental impacts such as eutrophication. Nitrogen removal is achieved by the combined action of nitrification and denitrification. Nitrification is performed by autotrophic, slow growing microorganisms that require oxygen and are inhibited in the presence of denitrifiers when oxygen and COD are available due to competition for oxygen. Denitrification however, performed by relatively fast growing heterotrophic bacteria, is inhibited by oxygen and requires COD. This implies that nitrification and denitrification are mutually exclusive. The supply of oxygen to a fresh wastewater, high in ammonia and COD, causes waste of both oxygen and COD. Conservation of COD is therefore critical to efficient wastewater treatment. The approach investigated in this study to achieve complete nitrogen removal was to physically separate the nitrification and denitrification biomasses into separate bioreactors, supplying each with appropriate conditions for growth and activity.
A storage driven denitrification sequencing batch biofilm reactor (SDDR) was established which exhibited a high level of COD storage (up to 80% of influent COD) as poly-B-hydroxybutyrate capable of removing >99% of nitrogen from wastewaters with a C/N ratio of 4.7 kg COD/kg N–NO3 –. The SDDR was combined in sequential operation with a nitrification reactor to achieve complete nitrogen removal. The multiple stage, multiple biomass reactor was operated in sequence, with Phase 1 - COD storage in the storage driven denitrification biofilm; Phase 2 - ammonia oxidation in the nitrification reactor; and Phase 3 - nitrate reduction using the stored COD in the storage driven denitrification reactor. The overall rate of nitrogen removal observed was up to 1.1 mmole NH3 L–1 h–1 and >99% of nitrogen could be removed from wastewaters with a low C/N ratio of 3.9 kg COD/kg N–NH3.
The multiple stage, multiple biomass system was limited in overall nitrogen removal the reduction in pH caused by nitrification. A parallel nitrification-denitrificatio (PND) reactor was developed in response to the pH control issue. The PND reactor was operated with Phase 1 – COD storage in the storage driven denitrification biofilm and Phase 2 – simultaneous circulation of reactor liquor between the denitrification and nitrification biofilms to achieve complete nitrogen removal and transfer of protons. The PND reactor performed competitively with the multistage reactor (removal of >99% nitrogen from wastewaters with feed ratios of 3.4 kg COD/kg N–NH3) without the need for addition of buffering material to oderate the pH.
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ABSTRACT: The performance of an activated sludge wastewater treatment process consisting of an aeration tank and a secondary settler has been studied. A tanks-in-series model with backflow was used for mathematical modeling of the activated sludge wastewater treatment process. Non-linear algebraic equations obtained from the material balances of MLSS (mixed liquor suspended solids or activated sludge), BOD (biological oxygen demand) and DO (dissolved oxygen) for the aeration tank and the settler and from the behavior of the settler were solved simultaneously using the modified Newton-Raphson technique. The concentration profiles of MLSS, BOD and DO in the aeration tank were obtained. The simulation results were examined from the viewpoints of mixing in the aeration tank and flow in the secondary settling tank. The relationships between the overall performance of the activated sludge process and the operating and design parameters such as hydraulic residence time, influent BOD, recycle ratio and waste sludge ratio were obtained.
Bioprocess and Biosystems Engineering 01/1999; 21(3):249-254. DOI:10.1007/s004490050672 · 2.00 Impact Factor
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ABSTRACT: In this paper the model of an ideal-displacement reactor for aluminum oxidation in saturated wet steam is presented. In particular, the ideal constant mode of this reactor is considered. Thermo- and gas-dynamic parameters of the reactor are calculated. Obtained parameters are optimized from the point of view of thermodynamic reactor effectiveness. The comparison of pilot experiments and theoretical results is also carried out. Analysis shows good computation and experiment agreement and concludes the appropriateness of obtained data using in development and optimization of energy plants based on aluminum oxidation reactors as steam-hydrogen generators. This work also gives some practical advices how to attain an ideal constant mode of the reactor of aluminum oxidation in saturated wet steam.
International Journal of Hydrogen Energy 03/2010; 35(5):1888-1894. DOI:10.1016/j.ijhydene.2009.12.061 · 3.31 Impact Factor
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