Article

Solid-state single-crystal-to-single-crystal transformation from a 2D layer to a 3D framework mediated by lattice iodine release.

Key Lab of Polyoxometalate Science, Department of Chemistry, Northeast Normal University, Changchun 130024, People's Republic of China.
Chemical Communications (impact factor: 6.17). 08/2012; 48(63):7859-61. DOI:10.1039/c2cc33831a
Source: PubMed

ABSTRACT We describe an exceedingly rare example of solid-state single-crystal-to-single-crystal transformation from a 2D layer to a known 3D framework via lattice iodine release, which involves the formation of a new Cu-O ligand bond and a change in the metal coordination geometry.

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Yuan-Chun He