Article

Sintering behavior and dielectric properties of BaTiO3 ceramics with glass addition for internal capacitor of LTCC

Particulate Materials Research Center, Department of Resources Engineering, National Cheng Kung University, Tainan, Taiwan, ROC; Department of Materials Science and Engineering, National United University, Miaoli, Taiwan, ROC; Department of Materials Science and Engineering, I-Shou University, Kaoshiung, Taiwan, ROC
Journal of Alloys and Compounds (Impact Factor: 2.73). 01/2008; 459:307-310. DOI: 10.1016/j.jallcom.2007.04.218

ABSTRACT The addition effects of ZnO–B 2 O 3 –SiO 2 (ZBS) glass on both the sintering behavior and dielectric properties of BaTiO 3 were investigated in developing low-temperature-fired BaTiO 3 -based ceramics for LTCC devices. X-ray diffractometer (XRD), scanning electron microscopy (SEM), and a dilatometer were used to examine the effect of ZBS glass on BaTiO 3 densification and the chemical reaction between the glass and BaTiO 3 . The results indicate that ZBS glass can be used as a sintering aid to reduce the sintering temperature of BaTiO 3 from 1300 to 900 • C without secondary phase formation. The dielectric properties of BaTiO 3 with ZBS glass sintered at 900 • C show a relative density of 95%, a high dielectric constant of 994, and a dielectric loss of 1.6%.

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May 23, 2014