Article

Copper-catalyzed decarboxylative C(sp2)-C(sp3) coupling reactions via radical mechanism.

Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, 215123, P. R. China.
Chemical Communications (impact factor: 6.17). 07/2012; 48(63):7847-9. DOI:10.1039/c2cc33203e
Source: PubMed

ABSTRACT We have successfully developed an example of copper-catalyzed decarboxylative C(sp(2))-C(sp(3)) coupling reactions via C-H functionalization for the first time. It is noteworthy that our catalytic system is very stable, low-cost, palladium-free, ligand-free, and easily accessible.

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Keywords

catalytic system
 
copper-catalyzed decarboxylative C(sp(2))-C(sp(3))
 
ligand-free
 

Hailong Yang