Article

C‐18‐coated silica particles as a surrogate for benthic uptake of hydrophobic compounds from bedded sediment

Environmental Toxicology and Chemistry (Impact Factor: 2.62). 10/2009; 15(12):2284 - 2289. DOI: 10.1002/etc.5620151224

ABSTRACT To simulate the bioaccumulation of neutral organic contaminants by infaunal benthos, the partitioning of polychlorinated biphenyls (PCBs) and polycyclic aromatic hydrocarbons (PAHs) between a contaminated estuarine sediment and admixed C-18-coated silica particles was measured. The concentrations of lower chlorinated PCB congeners (less than five chlorine atoms per molecule) on the C-18-coated silica particles reached apparent steady state within 300 h while congeners with greater numbers of chlorine atoms required much greater time periods (greater than 1 year) to reach apparent steady state. Polycyclic aromatic hydrocarbons showed less partitioning from sediment to the C-18 particles than PCB congeners, although the log Kow ranges of the compounds in these comparisons were similar. The biota sediment accumulation factors, defined as the lipid-normalized contaminant concentration in an exposed organism divided by the organic carbon-normalized contaminant concentration of the sediment, were calculated for these exposures using the C-18 of the particles as the lipid. The results from these exposures agreed closely with those measured in studies where living benthic organisms were exposed to contaminated sediment.

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