Article

Selective construction of Pd2Pt and PdPt2 triangles in a sandwich framework: carbocyclic ligands as scaffolds for a mixed-metal system.

Institute for Molecular Science, Okazaki, Aichi, 444-8787, Japan.
Chemistry (impact factor: 5.93). 06/2012; 18(29):8886-90. DOI:10.1002/chem.201201474 pp.8886-90
Source: PubMed

ABSTRACT Sandwich time! The mixed-metal triangular-trinuclear sandwich complexes of Pd(2)Pt and PdPt(2) were selectively synthesized. The Pd(2)Pt and PdPt(2) triangles in a cycloheptatrienyl sandwich framework were identified by (31)P NMR analyses of the tris-triphenylphosphine complexes (see scheme).

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Keywords

31)P NMR analyses
 
cycloheptatrienyl sandwich framework
 
mixed-metal triangular-trinuclear sandwich complexes
 
Sandwich time
 

Tetsuro Murahashi