Article

Linked Metal-cluster Systems: Isolation and Characterisation of {anti-[(p-cymene)RuCl]-μ-[κ2-P,P′;κ1-P′′-(PPh2CH2)3CMe]-[AuPt3(CO)3(PCy3)3]}(PF6)2

Journal of Cluster Science (impact factor: 0.92). 04/2012; 19(1):295-309. DOI:10.1007/s10876-007-0175-0 pp.295-309

ABSTRACT The new mixed-metal complex {anti-[(p-cymene)RuCl]-μ-[κ
2-P,P′;κ
1-P′′-(PPh2CH2)3CMe]-[AuCl]}PF6 and its cluster derivative {anti-[(p-cymene)RuCl]-μ-[κ
2-P,P′;κ
1-P′′-(PPh2CH2)3CMe]-[AuPt3(CO)3(PCy3)3]}(PF6)2 have been prepared and characterized. Notably, NMR spectroscopy and high resolution FT-ICR mass spectrometry, including a
tandem mass spectrometric analysis, demonstrated the formation of these compounds that was also confirmed by single crystal
X-ray diffraction analysis.

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Keywords

compounds
 
NMR spectroscopy
 
resolution FT-ICR mass spectrometry