Article

On the structural phase transition in rare earth elpasolites

Agfa Gevaert AG D-8000 München 70 FRG
Zeitschrift für Physik B Condensed Matter 08/1984; 55(3):219-226. DOI: 10.1007/BF01329014

ABSTRACT The structural phase transition in two representatives of the rare earth elpasolite fluorides, Rb2NaHoF6 and Rb2NaTmF6, are studied in detail. The symmetry of the soft mode is determined from Raman spectra, X-ray and neutron powder diffraction data to be
4
+
. From the temperature dependence of the elastic constants of both compounds, estimates of various phase transition parameters are given, e.g. strain soft mode coupling constant and soft mode frequency. The softening of the elastic constants forT>T

c
is explained by the strain coupling to the fluctuations of the soft mode coordinates. The energy of the soft phonon at the zone boundary is estimated from the data and compared with that of K2ReCl6. The phase transition mechanisms in rare earth elpasolites and hexahalometallates are discussed.

0 Bookmarks
 · 
41 Views
  • Source
    [Show abstract] [Hide abstract]
    ABSTRACT: The structural phase transition has been observed for the first time in the Rb2NaYF6 crystal and studied by EPR and optical spectroscopy. EPR spectra of Dy3+ and Yb3+ ions present as unintentional dopants in the nominally undoped crystal and forming tetragonal paramagnetic centers have been identified. A characteristic splitting of some optical lines has been observed in the temperature dependence of the Yb3+ optical spectra. It indicates the splitting of the cubic quartet energy levels of Yb3+ ions by the tetragonal crystal field. The empirical schemes of the energy levels for cubic and tetragonal paramagnetic centers of Yb3+ ions have been established and parameters of the corresponding crystal fields have been determined. The latter have been used for analyzing the crystal lattice distortions occurring in the vicinity of the Yb3+ ion during the phase transition. It has been established using the superposition model that the nearest octahedral environment of the Yb3+ ion is distorted as follows: the fluorine ions are rotated by the angle of 2.1° around the fourfold axis; the F− ions located symmetrically in the plane perpendicular to the rotation axis approach the dopant by 0.0014 nm, whereas the F− ions located on the rotation axis move away by 0.0028 nm. It has been concluded that the studied phase transition includes the critical rotations of the octahedral F groups and noncritical displacement of atoms in the rotated fluorine octahedra.
    Physical review. B, Condensed matter 03/2013; 87(11). · 3.77 Impact Factor
  • [Show abstract] [Hide abstract]
    ABSTRACT: The static and dynamic properties of cubic Rb2KInF6 crystals with elpasolite structure are calculated using a nonempirical method. Calculations are performed within a microscopic ionic-crystal model taking into account the deformation and polarization of ions. The deformation parameters of ions are determined by minimizing the total energy of the crystal. The calculated equilibrium lattice parameters agree satisfactorily with the experimental data. It is found that in the cubic phase there are vibrational modes that are unstable everywhere in the Brillouin zone. The eigenvectors of the unstablest mode at the center of the Brillouin zone of the cubic phase are associated with the displacements of F ions and correspond to rotations of InF6 octahedra. Condensation of this mode leads to a tetragonal distortion of the structure. In order to describe the Fm3m → I4/m phase transition, an effective Hamiltonian is constructed under the assumption that the soft mode whose eigenvector corresponds to octahedron rotation is local and coupled with homogeneous elastic strains. The parameters of the effective Hamiltonian are determined using the calculated crystal energy for the distorted structures due to soft-mode condensation. The thermodynamic properties of the system with this model Hamiltonian are investigated using the Monte Carlo method. The phase transition temperature is calculated to be 550 K, which is twice its experimental value (283 K). The tetragonal phase remains stable down to T=0 K; the effective Hamiltonian used in this paper thus fails to describe the second phase transition (to the monoclinic phase). Thus, the transition to the tetragonal phase occurs for the most part through octahedron rotations; however, additional degrees of freedom, first of all, the displacements of Rb ions, should be included into the effective Hamiltonian in order to describe the transition to the monoclinic phase.
    Physics of the Solid State 01/2001; 43(12):2290-2300. · 0.77 Impact Factor
  • Source
    [Show abstract] [Hide abstract]
    ABSTRACT: The pattern of lattice distortions occurring in the vicinity of Yb3+ ions during the transition of the Rb2NaYF6: Yb3+ crystal from the cubic to tetragonal phase has been revealed using all the parameters of the empirically found crystal fields for paramagnetic centers of the Yb3+ ions with cubic and tetragonal symmetry. It has been shown that the YbF6 octahedra are rotated about the fourfold axis through an angle approximately equal to 1.2°. Moreover, the octahedra themselves are deformed so that the F- ions symmetrically located in the plane perpendicular to the axis of rotation come close to the impurity ion at a distance of 0.0004 nm. The fluoride ions located on the axis of rotation, conversely, move away from the Yb3+ ion at a distance of 0.0005 nm. Based on the obtained results, it has been concluded that the total condensate of order parameters of the studied phase transition involves not only the critical rotations of octahedral groups but also the noncritical displacements of atoms in the rotated octahedra.
    Physics of the Solid State 01/2013; 55(12):2558-2565. · 0.77 Impact Factor