Synthesis and luminescence properties of ZnS:Mn/ZnS core/shell nanorod structures

Journal of Materials Science (Impact Factor: 2.31). 01/2009; 44(11):2792-2795. DOI: 10.1007/s10853-009-3367-1

ABSTRACT Mn-doped ZnS nanorods synthesized by solvothermal method were successfully coated with ZnS shells of various thicknesses.
The powder X-ray diffraction (XRD) measurements showed the ZnS:Mn nanorods were wurtzite structure with preferential orientation
along c-axis. Transmission electron microscopy images (TEM) revealed that the ZnS shells formed from small particles, growing
along a-axis orientation, which was proved by the XRD measurements. Room temperature photoluminescence (PL) spectra showed
that the intensity of Mn emission first increased and then decreased with the thickening of the ZnS shells. The effects of
ZnS shells on the luminescence properties of ZnS:Mn nanorods is discussed.

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