Article

Conformational dynamics of some short-chain biradicals in solutions

Applied Magnetic Resonance (impact factor: 0.75). 05/2012; 19(2):187-196. DOI:10.1007/BF03162273 pp.187-196

ABSTRACT Intramolecular electron spin exchange, as a function of temperature and the solvent nature, has been studied by X-band electron
paramagnetic resonance (EPR) spectroscopy in five short-chain flexible nitroxide biradicals. Certain thermodynamic parameters
of the conformational rearrangements were calculated from the EPR spectra. The process of spin exchange in short flexible
biradicals has some peculiarities in comparison with that in long-chain molecules.

0 0
 · 
1 Bookmark
 · 
62 Views
Data provided are for informational purposes only. Although carefully collected, accuracy cannot be guaranteed. The impact factor represents a rough estimation of the journal's impact factor and does not reflect the actual current impact factor. Publisher conditions are provided by RoMEO. Differing provisions from the publisher's actual policy or licence agreement may be applicable.

Keywords

biradicals
 
Certain thermodynamic parameters
 
conformational rearrangements
 
EPR
 
EPR spectra
 
Intramolecular electron
 
long-chain molecules
 
short-chain flexible nitroxide biradicals