Highly regioirregular polypropylene from asymmetric group 4 anilide(pyridine)phenoxide complexes.
Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125, USA.Chemical Communications (Impact Factor: 6.38). 05/2012; 48(53):6657-9. DOI: 10.1039/c2cc32806b
ABSTRACT Group 4 complexes containing an anilide(pyridine)phenoxide ligand and activated with methylaluminoxane (MAO) catalyze the formation of highly regioirregular polypropylene.
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ABSTRACT: A catalyst for the oligomerization of 1-hexene, generated by the activation of a benzimidazolylidene zirconium dibenzyl complex, switches to a polymerization catalyst on addition of a trialkylphosphine.Dalton Transactions 09/2013; · 4.10 Impact Factor
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