Article

An unexpected silver triflate catalyzed reaction of 2-alkynylbenzaldehyde with 2-isocyanoacetate.

Department of Chemistry, Fudan University, 220 Handan Road, Shanghai 200433, China.
Organic Letters (Impact Factor: 6.14). 05/2012; 14(11):2655-7. DOI: 10.1021/ol300901x
Source: PubMed

ABSTRACT An unexpected silver triflate catalyzed reaction of 2-alkynylbenzaldehyde with 2-isocyanoacetate provides an efficient route for the generation of isoquinolines. The reaction proceeds smoothly in air under mild conditions with high efficiency.

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