Dielectric and electromechanical properties of rare earth calcium oxyborate piezoelectric crystals at high temperatures

State Key Lab. of Crystal Mater., Shandong Univ., Jinan, China
IEEE Transactions on Ultrasonics Ferroelectrics and Frequency Control (Impact Factor: 1.5). 05/2011; DOI: 10.1109/TUFFC.2011.1881
Source: IEEE Xplore

ABSTRACT The electrical resistivity, dielectric, and electromechanical properties of ReCa4O(BO3)3 (ReCOB; Re = Er, Y, Gd, Sm, Nd, Pr, and La) piezoelectric crystals were investigated as a function of temperature up to 1000°C. Of the studied crystals, ErCOB and YCOB were found to possess extremely high resistivity (p): p >; 3 × 107 ω.cm at 1000°C. The property variation in ReCOB crystals is discussed with respect to their disordered structure. The highest electromechanical coupling factor κ26 and piezoelectric coefficient d26 at 1000°C, were achieved in PrCOB crystals, with values being on the order of 24.7% and 13.1 pC/N, respectively. The high thermal stability of the electromechanical properties, with variation less than 25%, together with the low dielectric loss (<;46%) and high mechanical quality factor (>;1500) at elevated temperatures of 1000°C, make ErCOB, YCOB, and GdCOB crystals promising for ultrahigh temperature electromechanical applications.

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    ABSTRACT: Pyroelectric properties of the monoclinic ReCa4O(BO3)3 (ReCOB, where Re is rare earth: Y, Gd, Nd, and Pr) single crystals were investigated by the charge integration method in the temperature range of 20°C to 180°C. The two independent pyroelectric coefficients p1 and p3 were measured and their temperature-dependent properties were studied; the pyroelectric p1 was found to be negative and decrease with increasing temperature, varying from -59.3, -64.2, -65.5, and -59.5 μC/(m2??°C) at 30°C to -52.9, -53.3, -46.6, and -50.5 μC/(m2??°C) at 180°C for YCOB, GdCOB, NdCOB, and PrCOB, respectively, whereas the positive coefficient p3 was observed to decrease from 11.6, 13.6, 23.5, and 31.0 μC/(m2??°C) at 30°C to 2.5, 7.1, 4.9, and 10.1 μC/(m2??°C) at 180°C, respectively. In addition, the ReCOB crystals were found to possess relatively high detectivity Fd, being 7.6 to 11.4 x 10-5 Pa-1/2 at 30°C, approximately two times that of commercial triglycine sulfate (TGS) and LiTaO3 crystals, with minimal variations up to 180°C, indicating the potential for use in thermal imaging applications.
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    ABSTRACT: High temperature piezoelectric crystals, YCa4O(BO3)3 (YCOB) possess relatively high piezoelectric activities (deff = ~7.8pC/N, keff= ~19%) and no phase transition prior to the melting point (~1500°C), indicating the potential use for high temperature sensing. In this work, growth of YCOB single crystals by using Czochralski (Cz) method was introduced and the temperature dependence of electro-elastic properties was investigated from 20 to 950°C, where the resonance frequencies relating to elastic compliances sE33 and sE55, were found to shift linearly with increasing temperature, with relatively large first order temperature coefficient being on the order of ~94ppm/°C. Of particular significance is that the lateral mode of (XY) and (XZ) crystal cuts were found not only possess relatively high electromechanical coupling factor (keff= ~15%) and piezoelectric coefficient (deff = ~4 pC/N), but also the temperature independence of electromechanical properties, demonstrating YCOB a good candidate for high temperature piezoelectric sensing.
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    ABSTRACT: High-temperature sensors are desirable for structural health monitoring and/or nondestructive evaluation of next-generation turbines, more efficient jet engines, and the furnace components of electrical power plants. Of all the investigated high-temperature piezoelectric materials, rare-earth calcium oxyborate crystals ReCa4O(BO3)3 (ReCOB, Re: rare-earth) exhibit attractive advantages for high-temperature piezoelectric sensing. In this paper, the electroelastic properties of different ReCOB piezoelectric crystals are investigated. The crosstalk between various vibration modes are discussed, from which the optimized crystal cuts are achieved. Furthermore, temperature dependences of the electrical resistivity, dielectric, elastic, piezoelectric, and electromechanical properties of ReCOB crystals are studied. Finally, the thermal properties, including thermal expansion, specific heat, and thermal conductivity at elevated temperatures are studied and compared with commercially available high-temperature piezoelectric crystals.
    IEEE Transactions on Ultrasonics Ferroelectrics and Frequency Control 08/2014; 61(8):1344-1356. · 1.50 Impact Factor


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Oct 14, 2014