Coordination of Phosphinoboranes R2PB(C6F5)(2) to Platinum: An Alkene-Type Behavior

Université de Toulouse , UPS, LHFA, 118 Route de Narbonne, F-31062 Toulouse, France.
Journal of the American Chemical Society (Impact Factor: 11.44). 04/2012; 134(15):6560-3. DOI: 10.1021/ja301929n
Source: PubMed

ABSTRACT The paucity of boron-containing heteroalkene complexes prompted us to explore the coordination of phosphinoboranes. The complexes {[R(2)PB(C(6)F(5))(2)]Pt(PPh(3))(2)} (R = Cy, t-Bu) were obtained by ethylene displacement. Spectroscopic and crystallographic data indicated symmetric side-on coordination of the phosphinoborane to Pt. Thorough analysis of the bonding situation by computational means revealed important similarities but also significant differences between the phosphinoborane and ethylene complexes.

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