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Adsorptive and photocatalytic properties of Ag-loaded BiVO4 on the degradation of 4-n-alkylphenols under visible light irradiation

Graduate School of Natural Science and Technology, Faculty of Pharmaceutical Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan; Faculty of Science, Science University of Tokyo, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan; Core Research for Evolutional Science and Technology, Japan Science and Technology Agency (CREST, JST), Kawaguchi, Saitama 332-0012, Japan
Catalysis Communications DOI:10.1016/j.catcom.2004.12.006 pp.185-189

ABSTRACT Silver fine-particles loaded on BiVO4 photocatalyst by an impregnation method remarkably improve adsorptive and photocatalytic performance on the degradation of long-chain alkylphenols such as 4-n-nonylphenol (NP) and 4-n-octylphenol (OP). The Ag-loaded BiVO4 powders strongly adsorb NP and OP, which is attributable to silver oxides (Ag2O and/or AgO) partly covered on the silver surface. The specific adsorption property disappears when the surface silver oxides are reduced in a H2 stream. Degradation rates and CO2 mineralization yields for NP are increased by the Ag loading on BiVO4.

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