Total synthesis of the terpenoid buddledone A: 11-membered ring-closing metathesis.
Department of Chemistry, University of Missouri-Columbia, Columbia, Missouri 65211, USA.Organic Letters (Impact Factor: 6.14). 03/2012; 14(7):1661-3. DOI:10.1021/ol300400x
ABSTRACT The first total synthesis of buddledone A was accomplished in seven steps from methyl ethyl ketone (MEK). The key step in the sequence featured an 11-membered ring formation by ring-closing metathesis.
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