Ion-Pair-Mediated Asymmetric Synthesis of a Configurationally Stable Mononuclear Tris(diimine)-Iron(II) Complex

Département de Chimie Organique Université de Genève quai Ernest Ansermet 30, 1211 Genève 4, Switzerland.
Angewandte Chemie International Edition (Impact Factor: 11.26). 07/2002; 41(13):2317-9. DOI: 10.1002/1521-3773(20020703)41:13<2317::AID-ANIE2317>3.0.CO;2-W
Source: PubMed


Configurational stability is conferred on the complex 1 (R=4-MeOC6H4) by the carefully designed tetradentate bis(1,10-phenanthroline) ligand. The resolution and asymmetric synthesis of 1 were readily achieved by using tris(tetrachlorobenzenediolato)phosphate(V) anions (2) as chiral auxiliaries. The picture shows the separation of the enantiomers of 1 by preparative ion-pair thin-layer chromatography.

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